Journal of the Chemical Society Faraday Transactions 1 Physical Chemistry in Condensed Phases · 1989 · 12 citations · 0 references
Materials ScienceChemical EngineeringConductivity StudyEngineeringIon ExchangeIonic ConductorNai SolutionsSolution (Chemistry)Physical ChemistryFuoss–justice EquationN-propanol–n-butanol MixturesChemistryChemical KineticsBinary N-propanol–n-butanol MixturesElectrochemistryIon Process
The electrical conductivity of NaI solutions in binary n-propanol–n-butanol mixtures within the whole composition range has been measured and analysed using the Fuoss–Justice equation. With increasing n-butanol content the limiting molar conductance decreased and the equilibrium constant of ion-pair formation increased. The standard dissolution enthalpies of NaI in the same binary mixtures (published earlier) have been recalculated taking into account the ion-association process.