Rapid Room-Temperature Synthesis and Characterization of Nanocrystals of a Prototypical Zeolitic Imidazolate Framework

Janosch Cravillon, Simon Münzer, Sven‐Jare Lohmeier, Armin Feldhoff, Klaus Huber, Michael Wiebcke

Chemistry of Materials · 2009 · 1.3K citations · 27 references

Concepts

Abstract

Simply reacting Zn(NO3)2·6H2O with an excess of 2-methylimidazole in methanol at room temperature yields well-shaped nanocrystals of ZIF-8 with a narrow size distribution. The rapid growth has been monitored by time-resolved static light scattering. Nanoscale ZIF-8 powder is microporous and thermally stable up to ca. 200 °C.

References

27