A novel luminescent 3D polymer containing silver chains formed by ligand unsupported Ag–Ag interactions and organic spacers

Daofeng Sun, Rong Cao, Jiabao Weng, Maochun Hong, Yucang Liang

Journal of the Chemical Society Dalton Transactions · 2002 · 103 citations · 21 references

Concepts

Abstract

A luminescent polymer [{Ag(H2btc)2}{Ag2(Hbtc)}]n with weak semiconductivity has been synthesized; structural analysis shows that the polymer possesses a 3D structure which contains silver chains formed by ligand unsupported Ag–Ag interactions and carboxylate spacers.

References

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