Concepedia

Novel CuI/tributyl phosphine catalyst system for amination of aryl chloridesElectronic supplementary information (ESI) available: experimental and analytical details (G.C. and NMR analysis). See http://www.rsc.org/suppdata/cc/b3/b308034j/

Nandkumar M. Patil, Ashutosh A. Kelkar, Zahid Nabi, Raghunath V. Chaudhari

Chemical Communications · 2003 · 23 citations · 0 references

Concepts

Natural SciencesChemical EngineeringChemistryCatalysisOrganic ChemistryReaction EngineeringCatalyst DesignCatalyst PreparationCatalyst SynthesisCatalytic MaterialsHeterocycle SynthesisHeterocyclic ChemistryOrganometallic CatalysisOrganometallic Catalyst Design

Abstract

A simple and efficient methodology for the synthesis of triarylamines from aryl chlorides in a single step has been demonstrated using a novel CuI/tributyl phosphine catalyst system with high activity and selectivity (80-87% yield).