Concepedia

Phosphabarrelene–rhodium complexes as highly active catalysts for isomerization free hydroformylation of internal alkenes

Bernhard Breit, Evelyn Fuchs

Chemical Communications · 2004 · 71 citations · 13 references

DOI

Concepts

Abstract

A new class of phosphabarrelene-rhodium catalysts is described which allows for the first time hydroformylation of internal alkenes with very high activity and which proceeds essentially free of alkene isomerization.

References

13

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Hydroformylation with a Rhodium/Bulky Phosphite Modified Catalyst. A Comparison of the Catalyst Behavior for Oct-1-ene, Cyclohexene, and Styrene

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Hydroformylation of less reactive olefins with modified rhodium catalysts

Piet W. N. M. van Leeuwen, C. F. ROOBEEK · Journal of Organometallic Chemistry · 1983 · 248 citations

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Structural systematics: the role of P-A .sigma.* orbitals in metal-phosphorus .pi.-bonding in redox-related pairs of M-PA3 complexes (A = R, Ar, OR; R = alkyl)

A.G. Orpen, Neil G. Connelly · Organometallics · 1990 · 188 citations

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Hydroformylation of Internal Olefins to Linear Aldehydes with Novel Rhodium Catalysts

Lars A. van der Veen, Paul C. J. Kamer, Piet W. N. M. van Leeuwen · Angewandte Chemie International Edition · 1999 · 186 citations

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