Concepedia

Caesium-templated lanthanoid-containing polyoxotungstates

Firasat Hussain, Bernhard Spingler, Franziska Conrad, Manfred Speldrich, Paul Kögerler, Colette Boskovic, Greta R. Patzke

Dalton Transactions · 2009 · 55 citations · 21 references

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Abstract

A family of novel lanthanoid-containing polytungstoarsenate(iii) polyanions with interesting structural features has been isolated: six lacunary {alpha-AsW(9)O(33)} building blocks comprising unusual pyramidal WO(5) units are templated by a caesium cation in a central cavity of the structure.

References

21

Bond-valence parameters obtained from a systematic analysis of the Inorganic Crystal Structure Database

I. D. Brown, D. Altermatt · Acta Crystallographica Section B Structural Science · 1985 · 9.4K citations

, , +16

Mononuclear Lanthanide Single-Molecule Magnets Based on Polyoxometalates

Murad A. AlDamen, J.M. Clemente-Juan, Eugenio Coronado et al. · Journal of the American Chemical Society · 2008 · 860 citations

, , +15

Self‐Assembly of Supramolecular Polyoxometalates: The Compact, Water‐Soluble Heteropolytungstate Anion [AsCe(H<sub>2</sub>O)<sub>36</sub>W<sub>148</sub>O<sub>524</sub>]<sup>76−</sup>

Knut Wassermann, Michael H. Dickman, Michael T. Pope · Angewandte Chemie International Edition in English · 1997 · 391 citations

, , +17

Giant metal-oxide-based spheres and their topology: from pentagonal building blocks to keplerates and unusual spin systems

Achim Müller, Paul Kögerler, Andreas Dress · Coordination Chemistry Reviews · 2001 · 384 citations

, , +12

Magnetic clusters from polyoxometalate complexes

J.M. Clemente-Juan, Eugenio Coronado · Coordination Chemistry Reviews · 1999 · 356 citations

, , +14