Concepedia

Palladium-Catalyzed Synthesis of <i>N</i>-Vinyl Pyrroles and Indoles

Mohammad Movassaghi, Alison E. Ondrus

The Journal of Organic Chemistry · 2005 · 60 citations · 29 references

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Concepts

Abstract

A stereospecific palladium-catalyzed N-vinylation of azaheterocycles with vinyl triflates is described. Cyclic and acyclic vinyl triflates along with nonnucleophilic azaheterocycles were found to be substrates for this palladium-catalyzed synthesis of N-vinyl pyrrole and indole derivatives.

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