Angewandte Chemie International Edition · 2014 · 128 citations · 44 references
Natural SciencesChemistryCatalysisComputational ChemistryOrganic ChemistryCarbene ComplexesCatalysis ModelingCoordination ChemistryHeterocyclic ChemistryMetal Ion CatalysisMetal-ligand BondingC - H Bond FunctionalizationCarbene Coordination ChemistryCation Coordination ChemistryElectrophilic CatalysisElectrophilic ReactivityMetal HydridesTransition-metal-catalyzed FunctionalizationZinc Catalysis
We present isolable examples of formal zinc hydride cations supported by N-heterocyclic carbene (NHC) donors, and investigate the dual electrophilic and nucleophilic (hydridic) character of the encapsulated [ZnH](+) units by computational methods and preliminary hydrosilylation catalysis.
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