Publication | Closed Access
Arylzinc Complexes as New Initiator Systems for the Production of Isobutene Copolymers with High Isoprene Content
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Citations
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References
2004
Year
EngineeringNew Initiator SystemsOrganic ChemistryChemistryArylzinc ComplexesPolymersPolymer MaterialIsobutene/isoprene CopolymerizationsOrganometallic CatalysisMinimal Cross-linkingIsoprene IncorporationPolymer ChemistryMaterials SciencePolymer EngineeringBiomolecular EngineeringPolymer ScienceHigh Isoprene ContentPolymer ReactionPolymer Synthesis
Better rubber: The initiator system [Zn(C6F5)2]/tBuCl for isobutene/isoprene copolymerizations (see scheme) gave products with high molecular weights, significantly increased isoprene incorporation, and minimal cross-linking.
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