Grain Growth Kinetics in Alumina–Zirconia (CeZTA) Composites

Abstract

Grain growth kinetics in alumina‐rich, zirconia–alumina composites have been examined as a function of volume fraction of zirconia. Both he microstructural scale and character alter during grain growth. Grain growth exponents between n = 3 and 4 were observed and have been rationalized in terms of current models for grain growth and particle coarsening. Grain growth constants wore measured and compared with available data. Coupled grain growth was observed in that the ratio of the alumina‐to‐zirconia grain size was constant, for a given zirconia content. This behavior is discussed in terms of the topological constraint present during growth and the observed microstructural evolution. The measured activation energies were consistent with boundary‐diffusion‐controlled grain growth.