Publication | Closed Access
A porous metal–organic cage constructed from dirhodium paddle-wheels: synthesis, structure and catalysis
63
Citations
103
References
2015
Year
Materials ScienceInorganic ChemistryChemical EngineeringExperimental SynthesisEngineeringPorous CarbonIntramolecular C–h AminationPorous Metal–organic CageOrganic ChemistryOrganometallic CatalysisCatalysisDirhodium Paddle-wheelsChemistryRh–rh BondsMetal-organic PolyhedronMetal-organic Frameworks
A porous metal–organic cage (MOC-Rh-<bold>1</bold>) with Rh–Rh bonds has been prepared, which can act as a heterogeneous catalyst and promote the intramolecular C–H amination of azides.
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