Angewandte Chemie International Edition · 2000 · 41 citations · 22 references
Natural SciencesChemistryMaterials ScienceInorganic ChemistryOrganic ChemistryCoordination ChemistryCrystal ChemistryLigand-based DesignMetal-ligand BondingTransition Metal ComplexesChalcogenide Structure ChemistryHydride FormationMetal HydridesPyrazole Chemistry
Two five-coordinate Al atoms are present in the planar Al2O2 core in 1, which was prepared from an aluminum dihydride and dioxane; unusually short Al−O bonds are also observed. The aluminum dihydride starting material reacts with Group 16 elements (S, Se, and Te) to provide further chalcogen-bridged aluminum hydrides.
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Alumoxanes: Synthesis, structures, complexes and reactions
S. Pasynkiewicz · Polyhedron · 1990 · 232 citations