Concepedia

Bromoiodinanes with an I(iii)–Br bond: preparation, X-ray crystallography and reactivity as electrophilic brominating agents

D. Christopher Braddock, Gemma Cansell, Stephen A. Hermitage, Andrew J. P. White

Chemical Communications · 2006 · 58 citations · 11 references

DOI

Concepts

Abstract

Bromoiodinanes--conveniently and directly prepared from iodobenzenecarbinols and N-bromosuccinimide, and characterised for the first time crystallographically--act as electrophilic bromine donors.

References

11

Readily accessible 12-I-5 oxidant for the conversion of primary and secondary alcohols to aldehydes and ketones

D. B. DESS, J. C. Martin · The Journal of Organic Chemistry · 1983 · 3.1K citations

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Hypervalent Iodine Chemistry in Synthesis: Scope and New Directions

Thomas Wirth · Angewandte Chemie International Edition · 2005 · 757 citations

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IBX—New Reactions with an Old Reagent

Thomas Wirth · Angewandte Chemie International Edition · 2001 · 199 citations

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Directed dilithiation of hexafluorocumyl alcohol - formation of a reagent for the facile introduction of a stabilizing bidentate ligand in compounds of hypervalent sulfur (10-S-4), phosphorus (10-P-5), silicon (10-Si-5), and iodine (10-I-3)

Edmund F. Perozzi, Ronald S. Michalak, Garret D. Figuly et al. · The Journal of Organic Chemistry · 1981 · 138 citations

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Synthesis and reaction of substituted arylalkoxyiodinanes: formation of stable bromoarylalkoxy and aryldialkoxy heterocyclic derivatives of tricoordinate organoiodine(III)

Ronald L. Amey, J. C. Martin · The Journal of Organic Chemistry · 1979 · 109 citations

, , +8