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Synthesis of two dihydropyrroloindoledione‐based copolymers for organic electronics
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2012
Year
Chemical EngineeringEngineeringMacromolecular EngineeringPolymer NanotechnologyOrganic ElectronicsPolymer ScienceResponsive PolymersConjugated UnitConjugated PolymerOrganic ChemistryAbstract TwoChemistryMolecular PolymerHybrid MaterialsBroad Absorption CopolymersPolymer ChemistryPolymer SynthesisPolymers
Abstract Two novel dihydropyrroloindoledione (DPID)‐based copolymers have been synthesized in a two directional approach and characterized (gel permeation chromatography (GPC), ultraviolet‐visible (UV–vis), cyclic voltammetry, and computational models). These planar, broad absorption copolymers show promise for use in organic electronics, with deep energy levels and low bandgaps. The two‐directional Knoevenagel condensation used demonstrates the versatility of DPID as a useful yet underexploited conjugated unit. © 2012 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem, 2013
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