Concepedia

Addition von Pentacarbonylrhenat an koordiniertes Benzol: Ein σ,π‐verbrückter, dynamischer Cyclohexadienyl‐Komplex, (OC)<sub>5</sub>Re‐μ‐(η<sup>1</sup>:η<sup>5</sup>‐C<sub>6</sub>H<sub>6</sub>Mn(CO)<sub>3</sub>

Burkhard Niemer, Manfred Steimann, Wolfgang Beck

Chemische Berichte · 1988 · 26 citations · 13 references

DOI

Abstract

Addition of Pentacarbonylrhenate to Coordinated Benzene:A δ,π‐Bridged, Fluxional Cyclohexadienyl Complex, (OC) 5 Re‐μ‐(η 1 :η 5 ‐C 6 H 6 )Mn(CO) 3 Nucleophilic addition of pentacarbonylrhenate to coordinated benzene in [(η 1 :η 5 ‐C 6 H 6 )Mn(CO) 3 ] + gives the η 1 :η 5 ‐cyclohexadienyl‐bridged title compound 1 . The structure of 1 has been determined by X‐ray analysis. 1 is the first example of fluxional behaviour in η 5 ‐cyclohexadienyl complexes.

References

13

.eta.5-Cyclohexadienyltricarbonylchromium(0) complexes from addition of carbon nucleophiles to .eta.6-benzenetricarbonylchromium(0). Formation, chemical and spectroscopic features, and x-ray diffraction analysis

M. F. SEMMELHACK, H. Tracy Hall, Roberta Farina et al. · Journal of the American Chemical Society · 1979 · 147 citations

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The electronic origin of geometrical deformations in cyclohexadienyl and cyclobutenyl transition metal complexes

Roald Hoffmann, Peter Hofmann · Journal of the American Chemical Society · 1976 · 131 citations

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Metallorganische Lewis-Säuren, XIV [1]. Ethylen-verbrückte Mangan- und Rheniumcarbonyle; Tieftemperatur-Röntgenstrukturanalyse von (OC)<sub>5</sub>ReCH<sub>2</sub>CH<sub>2</sub>Re(CO)<sub>5</sub> / Organometallic Lewis Acids, XIV [1]. Ethylene Bridged Manganese and Rhenium Carbonyls; Low Temperature X-Ray Structure of (OC)<sub>5</sub>ReCH<sub>2</sub>CH<sub>2</sub>Re(CO)<sub>5</sub>

Klaus Raab, Ulrich Nagel, Wolfgang Beck · Zeitschrift für Naturforschung B · 1983 · 72 citations · Full text

, , +14

Crystal and molecular structure of .pi.-cyclohexadienylmanganese tricarbonyl

Melvyn Rowen Churchill, Frederick R. Scholer · Inorganic Chemistry · 1969 · 71 citations

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Reaktionen von Carbonylmetall‐Anionen mit kationischen Olefinkomplexen: Ethylen‐verbrückte Komplexe von Molybdän, Wolfram und Rhenium

Bernhard Olgemöller, Wolfgang Beck · Chemische Berichte · 1981 · 54 citations