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The Photochemical Irradiation of R<sub>3</sub>SiH in the Presence of [(η<sup>5</sup>‐C<sub>5</sub>H<sub>5</sub>)Fe(CO)<sub>2</sub>CH<sub>3</sub>] in DMF Leads to Disiloxanes not Disilanes
43
Citations
6
References
2009
Year
Molecular SieveInorganic ChemistryChemical EngineeringOxygen SourceEngineeringPhotochemistryDmf LeadsDisiloxanes R3siosir3Physical ChemistryTertiary SilanesOrganometallic CatalysisChemistryHydrogenPhotochemical IrradiationRadiation ChemistryPhotophysical PropertyInorganic Synthesis
Not SiSi, rather SiOSi: Dimethylformamide (DMF) acts as an oxygen source in the efficient transformation of tertiary silanes (R3SiH; R3=Ph2Me, PhMe2, Et3) into disiloxanes R3SiOSiR3 in the presence of the catalyst [(η5-C5H5)Fe(CO)2CH3] (1; see scheme). This result contradicts a recently published related study, in which the formation of disilanes is reported.
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