A six-membered Cu3S3 ring in decakis(thiourea)tetracopper(I) hexafluorosilicate monohydrate: X-ray crystallographic structure determination

Abstract

The crystal structure of Cu4[SC(NH2)2]10-(SiF6)2,H2O has been determined and found to consist of six-membered rings of alternating Cu and S atoms connected by sulphur bridges to form chains, which are in turn interconnected via a Cu2S2 four-membered ring to form a three-dimensional polymer.