Green chemistry

TLDR

Ultrasound offers a green, non‑hazardous acoustic technology that induces cavitation, generating extreme local conditions and radical species, enabling milder reactions, improved yields, and the creation of porous materials and nanostructures. The review seeks to demonstrate how ultrasound can be harnessed to develop alternative, mild chemistry that replaces hazardous reagents and improves reaction outcomes. Ultrasound induces homolytic bond cleavage through acoustic waves, enabling alternative mild chemistry.

Abstract

Although the applications of ultrasound have long been known in both industry and academy, the “green” value of the non-hazardous acoustic radiation has been recognised by synthetic and environmental chemists only recently. The chemical and physical effects of ultrasound arise from the cavitational collapse which produce extreme conditions locally and thus induce the formation of chemical species not easily attained under conventional conditions, driving a particular radical reactivity. This rationale, accessible in a non-mathematical manner, anticipates the advantages of using this technology in a variety of processes that include milder reactions with improved yields and selectivities, easy generation of reactive species and catalysts or replacement of hazardous reagents. Sonication enables the rapid dispersion of solids, decomposition of organics including biological components, as well as the formation of porous materials and nanostructures. This review summarises how ultrasound can be harnessed to develop an alternative and mild chemistry, which parallels the ability of acoustic waves to induce homolytic bond cleavage.