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Regioselective Rhodium-Catalyzed Addition of Arylboronic Acids to Alkynes with a Pyridine-Substituted Water-Soluble Ligand
147
Citations
6
References
2001
Year
Arylboronic AcidsRegioselective Rhodium-catalyzed AdditionChemical EngineeringPyridine-substituted Water-soluble LigandEngineeringHeterocyclicHigh RegioselectivityOrganic ChemistryOrganometallic CatalysisCatalysisTrisubstituted AlkenesChemistryHomogeneous CatalysisBiomolecular Engineering
[reaction: see text] Alkynyl heteroaromatic compounds reacted with arylboronic acids to give addition products in the presence of [Rh(COD)Cl](2) and pyridine-substituted water-soluble ligand. The reactions proceed to give trisubstituted alkenes with high regioselectivity.
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