Concepedia

Double addition of H<sub>2</sub>to transition metal–borane complexes: a ‘hydride shuttle’ process between boron and transition metal centres

Nikolaos Tsoureas, Yu-Ying Kuo, M.F. Haddow, Gareth R. Owen

Chemical Communications · 2010 · 107 citations · 20 references

DOI

Concepts

Abstract

The addition of H(2) across a transition metal-borane bond is reported for the first time providing a mechanism for recharging borane functional groups to borohydride.

References

20

A new approach to the formal classification of covalent compounds of the elements

M.L.H. Green · Journal of Organometallic Chemistry · 1995 · 651 citations

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Transition‐Metal Complexes of Boron—New Insights and Novel Coordination Modes

Holger Braunschweig, Carsten Kollann, D. Rais · Angewandte Chemie International Edition · 2006 · 366 citations

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The Sting of the Scorpion: A Metallaboratrane

Anthony F. Hill, Gareth R. Owen, Andrew J. P. White et al. · Angewandte Chemie International Edition · 1999 · 351 citations · Full text

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Multidentate ligand systems featuring dual functionality

Istemi Kuzu, Ivo Krummenacher, Jens Meyer et al. · Dalton Transactions · 2008 · 214 citations

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Reactivity of the Metal→BX<sub>3</sub> Dative σ-Bond:  1,2-Addition Reactions of the Fe→BX<sub>3</sub> Moiety of the Ferraboratrane Complex [κ<sup>4</sup>-B(mim<sup>Bu</sup><sup><sup>t</sup></sup>)<sub>3</sub>]Fe(CO)<sub>2</sub>

Joshua S. Figueroa, J.G. Melnick, Gerard Parkin · Inorganic Chemistry · 2006 · 192 citations

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