The First Large‐Pore Vanadosilicate Framework Containing Hexacoordinated Vanadium

João Rocha, Paula Brandão, Zhi Lin, Michael W. Anderson, Viveka Alfredsson, Osamu Terasaki

Angewandte Chemie International Edition in English · 1997 · 77 citations · 7 references

Concepts

Abstract

A structure similar to that of microporous titanosilicate ETS-10 is reported for the first large-pore vanadosilicate framework containing stoichiometric amounts of hexacoordinated vanadium. A section of the high-resolution electron micrograph of the vanadosilicate is shown on the right.

References

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