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Sulphone-based elimination reactions in synthesis. Part 1. Moenocinol
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1983
Year
EngineeringKey Olefin-forming ReactionsOrganic ChemistryFluoride-induced EliminationSulphone-based Elimination ReactionsChemistryβ-Oxy SulphoneStereoselective SynthesisDerivative (Chemistry)Synthetic ChemistryBiomolecular Engineering
The fluoride-induced elimination of a β-phenylsulphonylsilane and the reductive elimination of a β-oxy sulphone are key olefin-forming reactions in a synthesis of moenocinol [(2Z, 6E, 13E)-3,8,8,14,18-pentamethyl-11-methylenenonadeca-2,6,13,17-tetraen-1-ol].