Synthesis of 2-spirocyclopropylglucose via condensation of erythrose with the lithium enolate of 2,6-di-tert=butyl-4-methylphenyl cyclopropanecarboxylate

Torsional strain involving partial bonds. The stereochemistry of the lithium aluminium hydride reduction of some simple open-chain ketones

M. CHEREST, Hugh Felkin, Nicole Prudent · Tetrahedron Letters · 1968 · 888 citations

Natural Sciences, Chemistry, Organic Chemistry +6

Unequivocal demonstration of the involvement of a glutamate residue as a nucleophile in the mechanism of a retaining glycosidase

Stephen G. Withers, R. Antony J. Warren, Ian P. Street et al. · Journal of the American Chemical Society · 1990 · 230 citations

Life Sciences, Biochemistry, Molecular Biology +8

Progeny of 2,3-unsaturated sugars. They little resemble Grandfather Glucose

Bert Fraser‐Reid · Accounts of Chemical Research · 1975 · 88 citations

Life Sciences, Biochemistry, Bioenergetics +5

Structure, Synthesis, and Properties of Some Persubstituted 1,2‐Dintroethanes. In Quest of Nitrocyclopropyl‐Anion Derivatives

Yasushi Kai, Paul Knochel, Stefan Kwiatkowski et al. · Helvetica Chimica Acta · 1982 · 80 citations

Natural Sciences, Chemistry, Organic Chemistry +13

Active site‐directed inhibition of galactosidases by conduritol C epoxides (1,2‐anhydro‐<i>EPI</i>‐and <i>NEO</i>‐inositol

Günter Legler, Monika Herrchen · FEBS Letters · 1981 · 62 citations · Full text

Life Sciences, Biochemistry, Biocatalysis +6