Physical Review Letters · 1973 · 64 citations · 1 references
Natural SciencesChemistryCondensed Matter PhysicsPolymer ChemistryPolymer MaterialsPartial MeltingPhase EquilibriaPhase TransitionsPolymer Phase BehaviorPolymer PhysicsPolymer SimulationIsing ModelIsing Model FormulationMeltingMelting BehaviorMelting Of Polymer MaterialsPolymer Chain StatisticsPolymer Melting BehaviorPolymer Melts
Heteropolymer melting corresponds to a low-temperature phase transition in a one-dimensional two-component Ising model. A leading-order approximation for an additive physical quantity in the melting region is introduced; it is intimately connected with the microscopic statistical herteropolymer structure. This allows one to derive the heteropolymer distribution function (over the length and composition of the sections) directly from experimental data.
1