Journal of the Chemical Society D Chemical Communications · 1971 · 22 citations · 0 references
Natural SciencesChemistryInorganic ChemistryOrganic ChemistryOrganometallic ChemistryCluster ChemistryCluster CompoundsCoordination ChemistryHeterocyclic ChemistryMetal-ligand BondingTransition Metal ComplexesCluster CarbonylsCluster SynthesisMetal-carbonyl ClustersMetal-metal Bonding In Carbonyl ClustersMetal-sulfur ClustersReactivity Of Metal CarbonylsRedox Chemistry Of ClustersTransition Metal Clusters
Low-valent phosphine–platinum complexes react with Fe2(CO)9, Ru3(CO)12, or H2Os(CO)4 to give heteronuclear cluster compounds of the types Fe2Pt(CO)10-nLn(n= 1 or 2), MPt2(CO)5L3, and M2Pt(CO)7L3(M = Ru, Os); the ligand L may be any one of a variety of substituted phosphines or phosphites, or triphenylarsine.