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Na<sub>2</sub>Li<sub>8</sub>[(UO<sub>2</sub>)<sub>11</sub>O<sub>12</sub>(WO<sub>5</sub>)<sub>2</sub>]: Three Different Uranyl‐Ion Coordination Geometries and Cation–Cation Interactions
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2006
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Inorganic ChemistryEngineeringHexagonal BipyramidalCation–cation InteractionsMain Group ChemistryChemistryHeterocycle ChemistryTitle CompoundUranyl InteractionsBiomolecular EngineeringIon StructureInorganic Compound
Uranyl interactions: The title compound is the first example of an actinide compound that contains three different actinyl-ion coordination geometries, namely, octahedral, pentagonal bipyramidal, and hexagonal bipyramidal. Strong cation–cation interactions between the uranyl ions lead to pentamers with a rather unusual configuration (see picture; U dark gray, O light gray).
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