Publication | Closed Access
Self‐Assembly of a Giant Tetrahedral 3 d–4 f Single‐Molecule Magnet within a Polyoxometalate System
171
Citations
53
References
2015
Year
Magnetic PropertiesEngineeringLow-dimensional MagnetismMolecular Self-assemblyPolymer-based MagnetChemistryMagnetic MaterialsPolymersMagnetismSingle-molecule MagnetMetal-organic PolyhedronMaterials ScienceInorganic ChemistryGiant Tetrahedral 3Polyoxometalate SystemSame Pom FrameworkMolecule-based MagnetNatural SciencesSelf-assemblyCoordination PolymerMolecule-based MaterialFunctional MaterialsCoordination Cluster Assemblies
A giant tetrahedral heterometallic polyoxometalate (POM) [Dy30 Co8 Ge12 W108 O408 (OH)42 (OH2 )30 ](56-) , which shows single-molecule magnet (SMM) behavior, is described. This hybrid contains the largest number of 4f ions of any polyoxometalate (POM) reported to date and is the first to incorporate two different 3d-4f and 4f coordination cluster assemblies within same POM framework.
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