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The Formation and an Unusual Dimerization of 2‐Mesityl‐1,1‐bis(trimethylsilyl)silene
33
Citations
9
References
1994
Year
Materials ScienceInorganic ChemistryMolecular SolidEngineeringSilicenePhysical ChemistryOrganic ChemistryUnstable Silene 1Main Group ChemistryUnusual DimerizationChemistryFormal RoleMesityl SubstituentGermanene
A formal role as monoene and also as diene by utilizing the mesityl substituent is possible for the unstable silene 1. In the absence of scavengers, 1 dimerizes in an unusual [2 + 4] reaction to form 2 as soon as it is prepared from (Me3Si)3SiC(OH)Mes.
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