Advanced Materials · 2015 · 228 citations · 30 references
Natural SciencesMaterials EngineeringMaterials ScienceElectronic MaterialsNanomaterialsSemiconductor MaterialsAnode MaterialsMemristive MaterialsNanoelectronicsOxide SemiconductorsSemiconductor Device MaterialsSemiconductor NanomaterialsConductive Filament FormationFilamentary Switching MechanismsOxide Memristive MaterialsOxygen VacanciesOxygen Vacancies In Metal OxidesOxygen Vacancy Formation
The filament in aAu/Ta2O5/Au system is analyzed and determined to be a nanoscaled TaO2−x filament. A shrunken anode localizes the filament formation and the defect boundary leads to faster accumulation of oxygen vacancies. The defect changes the switching domination between electron transport and oxygen-vacancy migration. The migration of oxygen vacancies limits the filament dynamics, indicating the crucial role played by oxygen defects. As a service to our authors and readers, this journal provides supporting information supplied by the authors. Such materials are peer reviewed and may be re-organized for online delivery, but are not copy-edited or typeset. Technical support issues arising from supporting information (other than missing files) should be addressed to the authors. Please note: The publisher is not responsible for the content or functionality of any supporting information supplied by the authors. Any queries (other than missing content) should be directed to the corresponding author for the article.
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