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Solution Equilibria of Enantiopure Helicates: The Role of Concentration, Solvent and Stacking Interactions in Self-Assembly
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1999
Year
Materials ScienceEnantioselective SynthesisEngineeringSupramolecular AssemblyMetal NanoparticlesNatural SciencesMolecular Self-assemblySelf-assemblySurface ScienceSilver HelicatesCoordination PreferencesPhysical ChemistryChemistrySolution EquilibriaCrystallographyStacking InteractionsBiophysicsSolution (Chemistry)
Many and varied are the effects which control the self-assembly of silver helicates, as illustrated schematically: besides the structure of the ligand and the coordination preferences of the metal, conditions such as the nature of the solvent and the concentration may also exert an influence.