Concepedia

Enantioselective Rh(I)-Catalyzed Cyclization of Arylboron Compounds onto Ketones

Darryl W. Low, Graham Pattison, Martin D. Wieczysty, Gwydion Churchill, Hon Wai Lam

Organic Letters · 2012 · 71 citations · 53 references

DOI

Concepts

Abstract

Rhodium complexes based upon chiral sulfinamide-alkene, TADDOL-derived phosphoramidite, or diene ligands catalyze cyclizations of arylboron compounds onto ketones, generating a variety of products containing five-, six-, or seven-membered rings with good yields and high enantioselectivities.

References

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