Angewandte Chemie International Edition · 2011 · 171 citations · 69 references
Natural SciencesChemical EngineeringChemistryCatalysisGreen ChemistryOrganic ChemistryCatalyst DesignCatalyst PreparationCatalytic MaterialsCatalytic MechanismsHeterocyclic ChemistryOrganic SynthesisCatalyst Structure - Activity RelationshipsCatalyst Structure-activity RelationshipsPyridine ChemistryPyridine SynthesisPyrrole ChemistryPyrrole Synthesis
Not only surprisingly facile, a hydrosilylation of pyridines under the catalysis of [Cp(iPr3P)Ru(NCCH3)2]+ has the advantages that it is 1,4-regioselective and reversible. The products can be transformed in a variety of ways (see scheme). The related complex [CpRu(NCCH3)3]+ catalyzes the two-hydrogen-atom reduction of phenanthroline by HSiMe2Ph/water.
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Asymmetric catalysis in organic synthesis
G. Jenner · Applied Catalysis A General · 1994 · 1.8K citations
Enantioselective Organocatalytic Reductive Amination
Richard Storer, Diane E. Carrera, Yike Ni et al. · Journal of the American Chemical Society · 2005 · 731 citations