Photoinduced Electron Transfer and Photovoltaic Response of a MDMO‐PPV:TiO<sub>2</sub> Bulk‐Heterojunction

Paul A. van Hal, Martijn M. Wienk, J.M. Kroon, W. J. H. Verhees, L.H. Slooff, W.J.H. van Gennip, Pascal Jonkheijm, René A. J. Janssen

Advanced Materials · 2003 · 257 citations · 19 references

Concepts

Abstract

Combining conjugated poylmers and TiO 2 in hybrid bulk‐heterojunctions is a promising method for producing novel solar cells. Here TiO 2 is introduced into a poly( p ‐phenylene vinylene) layer. Nanometer‐scale phase separation allows efficient photoinduced charge transfer between the two components. The films can be used as the active layer in a photovoltaic cell and provide external quantum efficiencies of up to 11 % (see Figure).

References

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