Concepedia

A new, highly selective synthesis of aromatic aldehydes by aerobic free-radical oxidation of benzylic alcohols, catalysed by n-hydroxyphthalimide under mild conditions. Polar and enthalpic effects

Francesco Minisci, Carlo Punta, Francesco Recupero, Francesca Fontana, Gian Franco Pedulli

Chemical Communications · 2002 · 105 citations · 12 references

DOI

Concepts

Abstract

A new selective synthesis of aromatic aldehydes is described, based on catalytic oxidation of benzyl alcohols with molecular oxygen at rt and atmospheric pressure.

References

12

Innovation of Hydrocarbon Oxidation with Molecular Oxygen and Related Reactions

Yasutaka Ishii, Satoshi Sakaguchi, Takahiro Iwahama · Advanced Synthesis & Catalysis · 2001 · 661 citations

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Oxidation of alcohols to aldehydes with oxygen and cupric ion, mediated by nitrosonium ion

M. F. SEMMELHACK, Christopher R. Schmid, David A. Cortés et al. · Journal of the American Chemical Society · 1984 · 628 citations

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Efficient and Selective Aerobic Oxidation of Alcohols into Aldehydes and Ketones Using Ruthenium/TEMPO as the Catalytic System

Arné Dijksman, Arturo Marino-González, Antoni Mairata i Payeras et al. · Journal of the American Chemical Society · 2001 · 533 citations

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Bond Dissociation Energies of O−H Bonds in Substituted Phenols from Equilibration Studies

Pamela Pedrielli, Gian Franco Pedulli, Salvatore Cabiddu et al. · The Journal of Organic Chemistry · 1996 · 291 citations

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Novel Catalysis by N-Hydroxyphthalimide in the Oxidation of Organic Substrates by Molecular Oxygen

Yasutaka Ishii, Kouichi Nakayama, Mitsuhiro Takeno et al. · The Journal of Organic Chemistry · 1995 · 289 citations

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