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Where is the Oxygen? Structural Analysis of α‐Humulene Oxidation Products by the Crystalline Sponge Method
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Citations
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References
2015
Year
EngineeringOxidation ResistanceOrganic ChemistryOxygen IsotopeScaffold-related CompoundsChemistryCrystalline Sponge MethodChemical EngineeringRedox ChemistryStereoselective SynthesisBiochemistryCatalysisα‐Humulene Oxidation ProductsNatural Product SynthesisEnantioselective SynthesisOxygen Reduction ReactionCyclic SesquiterpeneNatural SciencesStructural AnalysisChemical KineticsSynthetic Chemistry
Crystal structures of α-humulene, a cyclic sesquiterpene, and its oxidized subproducts, were analyzed by the crystalline sponge method. Regio- and stereochemistry, including absolute configuration when a chiral oxidant was applied, and the stable conformations of all the scaffold-related compounds were successfully determined for samples on a 5-50 μg scale.
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