Journal of the Chemical Society A Inorganic Physical Theoretical · 1971 · 32 citations · 0 references
Natural SciencesChemistryOrganometallic ChemistryPhysical ChemistryStructure-activity RelationshipsChemical BondingCoordination ChemistryLigand BindingMetal-ligand BondingOrganometallic BondingOrganometallic ReactivityLigand Effects On ReactivityMetal-ligand Bonding AnalysisPlatinum CompoundsSpectroscopic Characterization Of Metal-ligand Bonds
Compounds of formula [Pt(PPh3)2L](where L is an activated mono-olefin or monoalkyne) have been obtained by the direct interaction of Pt(PPh3)n(n= 2 or 3) or [Pt(PPh3)2(CH2:CH2)] with the activated ligands.The bonding between the platinum atom and the unsaturated ligands has been studied by a comparison of the stabilities of the adducts and on examination of the principal features of the i.r. and 1H n.m.r. spectra.