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An unprecedented organic–inorganic hybrid based on the first {Nb<sub>10</sub>V<sub>4</sub>O<sub>40</sub>(OH)<sub>2</sub>}<sup>12</sup><sup>−</sup>clusters and copper cations
70
Citations
34
References
2011
Year
Building BlocksEngineeringOrganic ChemistryThermogravimetric AnalysesChemistryUnprecedented Organic–inorganic HybridInorganic MaterialInorganic CompoundSingle-crystal X-ray DiffractionMetal-organic PolyhedronHybrid MaterialsMaterials ScienceInorganic ChemistryPhotochemistryCatalysisInorganic SynthesisCopper CationsMain Group ChemistryFunctional MaterialsOrganic-inorganic Hybrid Material
An unprecedented organic-inorganic hybrid {[Cu(6)L(6)(H(2)O)(3)][Nb(10)V(4)O(40)(OH)(2)]}(2)·13H(2)O (1) (L = 1,10-phenanthroline) containing the unreported {Nb(10)V(4)O(40)(OH)(2)}(12-) building blocks has been successfully synthesized and its photoluminescent properties, IR spectra, thermogravimetric analyses and single-crystal X-ray diffraction were investigated.
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