Angewandte Chemie International Edition in English · 1988 · 255 citations · 19 references
Natural SciencesChemistryInorganic ChemistryOrganometallic ChemistryCoordination ChemistryInorganic SynthesisMetal-ligand BondingOrganometallic ReactivityTransition Metal ChemistryTransition Metal ComplexesAcid-catalyzed HydrolysisAlkaline Earth Metal ChemistryChelate Complexation ReactionsComplexation ChemistryHydrolysisMetal Ion ChelationSynthetic Building Block Selection
An Mg4 tetrahedron constitutes the center of the chelate complex anion of 1, which is obtained in 85% yield from diethyl malonate, methylmagnesium iodide, and oxalyl chloride (1:1:0.25). Acid hydrolysis of 1 affords the free chelate ligand, which is an extremely interesting synthetic building block.
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Methods of Reactivity Umpolung
Dieter Seebàch · Angewandte Chemie International Edition in English · 1979 · 1.2K citations
Remarkable structures of lithium compounds
P. Rague von Schleyer · Pure and Applied Chemistry · 1984 · 178 citations · Full text