Polymer-layered silicate nanocomposites: Synthesis, properties and applications

TLDR

Polymer‑layered silicate nanocomposites offer a radical alternative to conventional filled polymers, achieving markedly improved mechanical, barrier, thermal, and flame‑retardant properties due to nanometer‑scale dispersion and serving as model systems for probing polymer structure and dynamics in confined environments. The authors employ both delaminated and intercalated hybrids to investigate polymer statics and dynamics across confinement distances from the polymer’s radius of gyration to its statistical segment length. The composites exhibit increased modulus and strength, reduced gas permeability, enhanced solvent and heat resistance, and lower flammability. © 1998 John Wiley & Sons, Ltd.

Abstract

Polymer nanocomposites, especially polymer-layered silicate (PLS) nanocomposites, represent a radical alternative to conventionally (macroscopically) filled polymers. Because of their nanometer-size dispersion, the nanocomposites exhibit markedly improved properties when compared with the pure polymers or conventional composites. These include increased modulus and strength, decreased gas permeability, increased solvent and heat resistance and decreased flammability. In addition to their potential applications, PLS nanocomposites are also unique model systems to study the structure and dynamics of polymers in confined environments. Using both delaminated and intercalated hybrids, the statics and dynamics of polymers confined over distances ranging from the radius of gyration of the polymer to the statistical segment length of the chains can be studied. © 1998 John Wiley & Sons, Ltd.