Publication | Closed Access
Barium Dibenzopentalenide as a Main‐Group Metal η<sup>8</sup> Complex: Facile Synthesis from 1,4‐Dilithio‐1,3‐butadienes and Ba[N(SiMe<sub>3</sub>)<sub>2</sub>]<sub>2</sub>, Structural Characterization, and Reaction Chemistry
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Citations
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References
2013
Year
Materials ScienceInorganic ChemistryReaction ChemistrySingle-crystal X-ray AnalysisEngineeringInorganic CompoundFacile SynthesisMain Group ChemistryChemistryBarium DibenzopentalenidesSynthetic ChemistryInorganic SynthesisBarium Dibenzopentalenide
Transmetalation of 1,4-dilithio-1,3-butadienes with Ba[N(SiMe3)2]2 gave barium dibenzopentalenides, which were structurally characterized by single-crystal X-ray analysis. A preliminary study of the reaction chemistry of thus obtained barium dibenzopentalenides demonstrated that synthetically useful applications can be expected.
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