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High-valent metalloporphyrin, Fe(tpp)OTf, catalyzed rearrangement of α,β-epoxy ketones into 1,2-diketones
85
Citations
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References
2002
Year
Chemical EngineeringTetraphenylporphyrin TriflateEngineeringHigh-valent MetalloporphyrinOrganic Chemistryβ-Epoxy KetonesOrganometallic CatalysisCatalysisChemistryAsymmetric CatalysisCatalytic SynthesisSelective Rearrangement
Iron(III) tetraphenylporphyrin triflate, Fe(tpp)OTf, works as an efficient and characteristic Lewis acid catalyst in the selective rearrangement of α,β-epoxy ketones into 1,2-diketones.
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