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Adsorption of thiosemicarbazide on copper cathodes
12
Citations
10
References
1986
Year
Materials ScienceChemical EngineeringStandard Free EnergyEngineeringSurface ChemistryCopper CathodesChemisorptionPhysical ChemistryOrganic ChemistryTsc MoleculeCatalysisAdsorptionChemistryWater MoleculesSurface ReactivityElectrochemistry
Abstract The adsorption of thiosemicarbazide (TSC) on cathodically polarised copper is studied. The adsorption follows the Flory‐Huggins and the Bockris‐Swinkels isotherms with a standard free energy of adsorption of about 20kJmol −1. Four water molecules are displaced by each adsorbing TSC molecule. This is explained on the basis of molecular models.
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