Hot‐Pressing Method to Consolidate <scp> <scp>Gd</scp> </scp> ₃ ( <scp> <scp>Al</scp> </scp> , <scp> <scp>Ga</scp> </scp> ) ₅ <scp> <scp>O</scp> </scp> ₁₂ : <scp> <scp>Ce</scp> </scp> Garnet Scintillator Powder for use in an <scp>X</scp> ‐ray <scp>CT</scp> Detector

Abstract

We have developed a hot‐pressing method for consolidating garnet scintillator powder of composition Gd 3 ( Al , Ga ) 5 O 12 : Ce . Thermodynamic analysis revealed that gallium oxide, which was a constituent of the garnet scintillator powder, would react with the graphite mold beginning at 950°C and would be reduced to gallium metal. To prevent this reaction during hot‐pressing, a reaction barrier material was placed between the graphite mold and the scintillator powder. As for the reaction barrier material, 3 Gd AlO 3 – Al 2 O 3 powder calcined at 1100°C was found to be suitable because the material provided two important characteristics: the same thermal expansion coefficient as the scintillator material and good sinterability. The Gd 3 ( Al , Ga ) 5 O 12 :Ce garnet scintillator powder was hot pressed at 1475°C for 4 h in vacuum, followed by annealing at 1300°C for 4 h in oxygen atmosphere. The thus obtained garnet scintillator successfully satisfied the necessary requirements for use in an X ‐ray computed tomography detector.