Preparation and characteristics of nonflammable polyimide materials

Abstract

The thermal and flame-retardant properties of homo- and copolyimides were evaluated. Those containing sulfone linkages in the backbone were found to be more flame retardant. Both properties were dependent on the composition. A polyimide/silica nanocomposite was obtained through sol–gel processing. The effects of the addition of silica on the dispersion, interfacial adhesion, fire resistance, mechanical properties, and thermal stability of the composites were investigated. SEM analysis showed a good dispersion of silica with a diameter of 50–300 nm in the organic matrices. The addition of silica increased the fire retardancy and mechanical properties of the composites. © 2000 John Wiley & Sons, Inc. J Appl Polym Sci 75: 384–389, 2000