Angewandte Chemie International Edition · 2011 · 185 citations · 41 references
Natural SciencesChemical EngineeringChemistryCatalysisNanomaterialsNanotechnologyCatalyst DesignCatalytic MaterialsCatalytic MechanismsCatalytic Reaction EngineeringNanocatalysisNanotubesCatalytic Hybrid MaterialsCatalytic NanomaterialsMild Reaction ConditionsOxidationSilane Functionalization
Turning over silanes: The first nanotube-based catalytic system for silane oxidation is reported (see scheme). The reusable gold–nanotube hybrid cleanly oxidizes both alkyl and aryl silanes in high yields, under mild reaction conditions, and compares most favorably to any other catalytic system in terms of overall efficacy and turnover values. Detailed facts of importance to specialist readers are published as ”Supporting Information”. Such documents are peer-reviewed, but not copy-edited or typeset. They are made available as submitted by the authors. Please note: The publisher is not responsible for the content or functionality of any supporting information supplied by the authors. Any queries (other than missing content) should be directed to the corresponding author for the article.
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