Advanced Materials · 2010 · 817 citations · 49 references
Materials ScienceCarbon SequestrationChemical EngineeringEngineeringPorous CarbonCarbonizationPolymer GelOrganic ChemistryCatalysisAdsorptionChemistryPolymerization CatalystNitrogen SourceCatalytic ProcessRapid SynthesisPolymer ChemistryPolymers
A polymer gel derived from resorcinol and formaldehyde can be prepared in around 5 min using lysine as polymerization catalyst and nitrogen source. After pyrolysis of this polymer gel, a new type of nitrogen-containing carbon monolith was obtained (see figure), which exhibits the highest CO2-adsorption capacity to date of up to 3.13 mmol g−1 at room temperature.
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Evolution of nitrogen functionalities in carbonaceous materials during pyrolysis
J.R. Pels, Freek Kapteijn, Jacob A. Moulijn et al. · Carbon · 1995 · 2K citations