Organic Letters · 2000 · 155 citations · 22 references
Natural SciencesChemistryCatalysisOrganic ChemistryCatalyst DesignLigand-based DesignAsymmetric CatalysisAsymmetric Catalyst DesignAsymmetric SynthesisChiral Catalyst DesignChiralityEnantioselective CatalysisEnantioselective Catalyst DesignEnantioselective Synthesis
[figure: see text] Ferrocene-modified chiral pocket ligands have been studied in the palladium-catalyzed asymmetric alkylation of simple ketone enolates, in which (R,R,Sp,Sp)-1 containing two pairs of matched chiralities, central chirality and planar chirality, behaved very efficiently in this reaction and up to 95% ee value was achieved.
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Asymmetric catalysis in organic synthesis
G. Jenner · Applied Catalysis A General · 1994 · 1.8K citations
Methodology for the construction of quaternary carbon centers
Stephen F. Martin · Tetrahedron · 1980 · 379 citations
Asymmetric Arylation of Ketone Enolates
Jens Åhman, John P. Wolfe, Malisa V. Troutman et al. · Journal of the American Chemical Society · 1998 · 291 citations