Concepedia

Carbonylation of the simplest persistent diaminocarbene

Tim Schulz, Christian Färber, Michael Leibold, Clemens Bruhn, Wolfgang Baumann, Detlef Selent, Timo Porsch, Max C. Holthausen, Ulrich Siemeling

Chemical Communications · 2013 · 31 citations · 29 references

DOI

Concepts

Abstract

The reactions of the acyclic diaminocarbenes (Me2N)2C and (Ph2N)(iPr2N)C with CO proceed in a 2 : 1 stoichiometric ratio, affording unprecedented betainic oxyallyl species of type [(R2N)2C]2CO.

References

29

Structure and Reactivity of Lithium Enolates. From Pinacolone to Selective <i>C</i>‐Alkylations of Peptides. Difficulties and Opportunities Afforded by Complex Structures

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, , +8

The (4+3)-cycloaddition reaction: simple allylic cations as dienophiles

Michael Harmata · Chemical Communications · 2010 · 308 citations

, , +14

Bis(diisopropylamino)carbene

Roger W. Alder, Paul R. Allen, Martin J. Murray et al. · Angewandte Chemie International Edition in English · 1996 · 305 citations

, , +3

Enantioselective Alkynylbenzaldehyde Cyclizations Catalyzed by Chiral Gold(I) Acyclic Diaminocarbene Complexes Containing Weak Au–Arene Interactions

Sachin Handa, LeGrande M. Slaughter · Angewandte Chemie International Edition · 2012 · 257 citations

, , +11

The (4+3)-cycloaddition reaction: heteroatom-substituted allylic cations as dienophiles

Michael Harmata · Chemical Communications · 2010 · 229 citations

, , +14