Publication | Closed Access
Solvothermal synthesis of [Cr10(μ-O2CMe)10(μ-OR)20] ‘chromic wheels’ with antiferromagnetic (R = Et) and ferromagnetic (R = Me) Cr(iii)···Cr(iii) interactions
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Citations
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References
2001
Year
Materials ScienceInorganic ChemistryMagnetismMagnetic PropertiesSolvothermal TechniquesEngineeringNatural SciencesCoordination ComplexSolvothermal SynthesisFunctional MaterialsHigh YieldMolecular ComplexChemistryMagnetic MaterialsInorganic SynthesisDecanuclear Cyclic CrInorganic Compound
Two decanuclear cyclic Cr(III) complexes have been synthesised in high yield by solvothermal techniques: magnetic susceptibility studies reveal ferromagnetic Cr⋯Cr exchange in one, and antiferromagnetic Cr⋯Cr exchange in the other.
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