Concepedia

Aerobic oxidative N-dealkylation of tertiary amines in aqueous solution catalyzed by rhodium porphyrins

Zhen Ling, Lianghui Liu, Bing Wu, Xuefeng Fu

Chemical Communications · 2012 · 68 citations · 45 references

DOI

Concepts

Abstract

Aerobic oxidative N-dealkylation of a variety of aliphatic tertiary amines and anilines catalyzed by rhodium(III) tetra (p-sulfonatophenyl) porphyrin ((TSPP)Rh(III)) is achieved in aqueous solution using dioxygen as the sole oxidant.

References

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